How quickly should you reply to clients?
When a client has a deadline, the cost of waiting depends on which decision is stuck.

If your work allows it, agree a response window clients can plan around and a separate route for issues that cannot wait. Base both on what happens when a reply is delayed and what you can reliably offer while doing the work they hired you for.
What actually needs a quick response?
Suppose you are an independent adviser helping a client prepare a workshop. The client sends a question about the slides and another message saying the meeting room is no longer available. You can reply to the slide question during your next email window. The room problem may need a call because someone has to make a decision before participants arrive.

Look at a few messages from a normal week. For each one you answered immediately, ask what would have happened if you had waited until later that day. Some answers will uncover a real dependency. Others will show that the rush came from seeing the message and feeling obliged to clear it. That gives you a better basis for agreeing a response time than the number of unread emails.
How to agree a response window
Pick an ordinary window you could keep even on a busy day. Tell the client when to expect an acknowledgement and how to reach you when a shared deadline is at risk. If you need time to investigate, acknowledge the message and say when you expect to come back with an answer.
Check the agreement before proposing a change. If the client pays for rapid support, those terms matter. If quick replies have become a habit and the client relies on them, talk it through before changing how you work. You may learn that the client only needs you to be reachable on the days when a decision is due.
How to tell if the arrangement works
Try the agreement with one client for a week. At the end, ask whether a decision was held up and whether anyone had to chase for a reply. Look at what happened on your side too. If you still checked messages between every task, see whether the problem was a real exception or uncertainty about what you had agreed.

One urgent request may justify a clearer way to reach you. A steady flow of urgent requests may call for a conversation about what support the client needs and what you can offer. If the new window worked for both sides, you have an example to draw on in your next client conversation.
Business coaching can give you time to work through decisions like this and decide how to serve clients in a way that fits the life you want to live.